In glibc, FILE is typedef'ed in bits/types/struct_FILE.h:
typedef struct _IO_FILE FILE;
_IO_FILE is a struct that is defined in /usr/include/bits/types/struct_FILE.h:
struct _IO_FILE
{
int _flags; /* High-order word is _IO_MAGIC; rest is flags. */
/* The following pointers correspond to the C++ streambuf protocol. */
char *_IO_read_ptr; /* Current read pointer */
char *_IO_read_end; /* End of get area. */
char *_IO_read_base; /* Start of putback+get area. */
char *_IO_write_base; /* Start of put area. */
char *_IO_write_ptr; /* Current put pointer. */
char *_IO_write_end; /* End of put area. */
char *_IO_buf_base; /* Start of reserve area. */
char *_IO_buf_end; /* End of reserve area. */
/* The following fields are used to support backing up and undo. */
char *_IO_save_base; /* Pointer to start of non-current get area. */
char *_IO_backup_base; /* Pointer to first valid character of backup area */
char *_IO_save_end; /* Pointer to end of non-current get area. */
struct _IO_marker *_markers;
struct _IO_FILE *_chain;
int _fileno;
int _flags2;
__off_t _old_offset; /* This used to be _offset but it's too small. */
/* 1+column number of pbase(); 0 is unknown. */
unsigned short _cur_column;
signed char _vtable_offset;
char _shortbuf[1];
_IO_lock_t *_lock;
#ifdef _IO_USE_OLD_IO_FILE
};